Phosphorus-Based FR

Phosphorus-Based FR

Tris(1-chloro-2-propyl) phosphate (TCPP)

  • CAS No.13674-84-5
Tris(1-chloro-2-propyl) phosphate (TCPP)
  • Chemical Formula: C9H18Cl3O4P
  • Molecular Weight: 327.58 g/mol
  • CAS Number: 13674-84-5
  • Appearance: Colorless to light yellow liquid
  • Flame Retardant Type: Organic, halogenated phosphorus-based

Key Flame Retardant Properties:

  • Phosphorus-Based Mechanism: TCPP functions as a phosphorus-based flame retardant, releasing phosphoric acid upon heating, which acts to suppress combustion and promote the formation of a protective char layer.
  • Chlorine-Containing Structure: The chlorine atoms in TCPP also help to interrupt the combustion process by releasing hydrochloric acid when exposed to heat, further slowing the spread of flames.
  • Effective in Flexible and Rigid Polymers: Suitable for both flexible and rigid polymer systems, providing versatile flame retardant performance.

Advantages:

  • Effective Flame Retardant: TCPP is highly effective at low loading levels, providing excellent flame retardant properties for various materials.
  • Versatile Application: Works well in a wide range of polymers, including flexible and rigid foams, coatings, and plastics.
  • Improved Smoke Suppression: Reduces the generation of smoke and toxic gases during combustion, contributing to better fire safety.
  • Low Toxicity and Low Migration: Compared to other halogenated flame retardants, TCPP has lower toxicity and lower migration rates, making it safer in many applications.
  • Cost-Effective: TCPP is a relatively cost-effective flame retardant, suitable for a broad range of applications without significantly affecting the properties of the base material.

Applications:

  • Polyurethane Foams: Commonly used in flexible and rigid foams for furniture, automotive seating, and insulation.
  • Textiles: Applied to fabrics for flame resistance in upholstery, carpets, and protective clothing.
  • Electrical & Electronics: Provides flame retardancy in electrical insulation materials, wires, and cables.
  • Building Materials: Used in coatings, sealants, and construction materials to enhance fire resistance.
  • Automotive: Added to automotive interior materials, including seat cushions and headliners, for better fire safety.

Processing Considerations:

  • Compatibility: TCPP can be used with a variety of polymers, including polyurethanes, polystyrene, and polyesters. It is also compatible with other flame retardants for synergistic effects.
  • Loading Levels: Typically used in concentrations ranging from 5–20%, depending on the desired flame retardant properties and the application material.
  • Processing Temperature: TCPP can be processed at temperatures typically used in polymer manufacturing (around 200–250°C), but excessive heat should be avoided to maintain its effectiveness.
  • Handling & Safety: While TCPP is less toxic compared to many halogenated flame retardants, proper safety precautions should be followed when handling to avoid exposure to fumes or skin contact.