Phosphorus-Based FR

Phosphorus-Based FR

Ammonium Polyphosphate (APP)

  • CAS No.68333-79-9
Ammonium Polyphosphate (APP)
  • Chemical Formula: (NH₄)₂n+2PnO₃n+1
  • Molecular Weight: Varies based on polymerization degree
  • CAS Number: 68333-79-9
  • Appearance: White to off-white granular or powder form
  • Flame Retardant Type: Inorganic, phosphorus-based

Key Flame Retardant Properties:

  • Phosphorus-Based Mechanism: APP releases phosphoric acid and ammonia when exposed to heat, which acts to suppress combustion and promote char formation.
  • Endothermic Decomposition: Absorbs heat during decomposition, helping to cool the material and slow down combustion.
  • Promotes char Layer Formation: Forms a stable, insulating char layer that acts as a protective barrier to flames, slowing down the spread of fire.
  • Synergistic Effect: Often used in combination with other flame retardants or additives (e.g., melamine) to improve performance.

Advantages:

  • Halogen-Free & Eco-Friendly: Ammonium polyphosphate is a halogen-free, non-toxic solution, making it safe for both humans and the environment.
  • Improved Flame Retardancy: High efficiency even at low loadings, providing excellent flame retardant properties in various materials.
  • Low Smoke & Toxic Gas Emission: Reduces the release of toxic gases and smoke during combustion.
  • Thermal Stability: Suitable for use in a wide range of materials with moderate to high processing temperatures.

Applications:

  • Plastics & Polymers: Widely used in polyamides (PA), polyesters (PET, PBT), polyolefins (PP, PE), and engineering plastics like polycarbonate (PC).
  • Textiles & Fabrics: Used in flame-retardant textiles and fabrics for protective clothing, industrial fabrics, and upholstery.
  • Construction Materials: Flame retardant in building materials like insulation boards, coatings, adhesives, and sealants.
  • Electrical & Electronics: Provides flame resistance to wires, cables, circuit boards, and various electronic components.
  • Rubber & Elastomers: Enhances flame retardancy in rubber compounds, especially for automotive and industrial applications.

Processing Considerations:

  • Particle Size & Dispersion: Fine particles improve dispersion in polymers, and surface-treated APP can enhance compatibility with various substrates.
  • Loading Levels: Typically used at concentrations of 5–25%, depending on the desired level of flame retardancy and the application material.
  • Compatibility: Works well with other flame retardants, including melamine, for synergistic effects.
  • Thermal Decomposition: Decomposes at higher temperatures (above 250°C), making it suitable for polymers processed at moderate to high temperatures.